Synthesis Optimization and Performance Test of Environmentally Friendly Renewable Poly(HMA-co-BMA-co-MA) Oil Absorbing Microspheres
DOI:
https://doi.org/10.54691/sjt.v5i2.4128Keywords:
Acrylate; Suspension Polymerization; Oil-absorbing Resin; Orthogonal Experiment.Abstract
In this study, butyl methacrylate (BMA), methyl acrylate (MA), cetyl methacrylate (HMA) as monomers, cetyl trimethyl ammonium bromide (CTAB) as dispersant, benzoyl peroxide (BPO) as initiator,N, n-methylene diacrylamide (MBA) as crosslinking agent, A kind of ternary oil absorbing resin was prepared by suspension polymerization. The range of long chain monomer (HMA), initiator (BPO), crosslinking agent (MBA) and surfactant (CTAB) was optimized by single factor experiment, and the best resin Poly (HMA-co-BMA-Co-MA) was obtained by orthogonal experiment design. The structure was analyzed by FR-IR, the microstructure of the resin was observed by SEM, and the stability of the resin was evaluated by TG. The experiment showed that the influence degree of reaction factors was as follows: long chain monomer amount > initiator amount > crosslinking agent amount > dispersant amount. The optimal synthesis conditions were: long chain monomer =25wt%, initiator =1wt%, crosslinking agent =1.1wt%, dispersant =0.030g.
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References
Zhu, X., et al., A versatile approach to produce superhydrophobic materials used for oil-water separation[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2014. 432: p. 105-108.
Wang, Y., et al., Synthesis and oil absorption of biomorphic MgAl Layered Double Oxide/acrylic ester resin by suspension polymerization[J]. Chemical Engineering Journal, 2016. 284: p. 989-994.
Ewaid, S.H., et al., Acute toxicity of the water chlorination byproduct (chloroform) in male mice[J]. AIP Conference Proceedings, 2020(No.1): p. 1-6.
Yuan, H., et al., Demulsification of Water-Containing Crude Oil Driven by Environmentally Friendly SiO2@CS Composite Materials[J]. Energy & Fuels, 2020. 34(7): p. 8316-8324.
Zhao, B., et al., Eco-friendly separation layers based on waste peanut shell for gravity-driven water-in-oil emulsion separation[J]. Journal of Cleaner Production, 2020. 255: p. 120184.
Liu, C., et al., Precontrol of algae-induced black blooms through sediment dredging at appropriate depth in a typical eutrophic shallow lake[J]. ECOLOGICAL ENGINEERING, 2015. 77: p. 139-145.
Liang, Y., D. Wang and H. Chen, Preparation of High Oil Absorption Resins by Suspended Emulsion Polymerization and Their Properties[J]. Separation science and technology, 2013. 48(13): p. 1977-1981.
Zhang, C.Z.C.S., et al., Synthesis of MnO2/poly(n-butylacrylate-co-butyl methacrylate-co-methyl methacrylate) hybrid resins for efficient oils and organic solvents absorption[J]. Journal of Cleaner Production, 2017: p. 398-406.
Sup, L.Y.S., et al., Synthesis and Absorption Performance of Acrylic Ester and Hollow Fiber MgO Nanoparticle Resin Composite[J]. Polymer-Plastics Technology and Engineering, 2017(No.17): p. 1857-1865.
Kong, Synthesis of polyacrylate oil absorbent resin and its application in the treatment of oil-bearing wastewater [D]. Beijing University of Chemical Technology. 2019.
Bu, X., et al., Fabrication of porous carbon nitride foams/acrylic resin composites for efficient oil and organic solvents capture[J]. Chemical Engineering Journal, 2019. 355: p. 299-308.
Ding et al., Development and research progress of oil-absorbing materials [J]. Industrial Water Treatment, 2017. 37(07): p. 10-14.
Liu, Synthesis and Characterization of novel polymer oil absorbent resin [D]. China University of Petroleum (East China).2013.
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