Progress in the Preparation and Application of SnSe Thin Films

Authors

  • Tianhao Li
  • Mengli Li

DOI:

https://doi.org/10.6911/WSRJ.202503_11(3).0016

Keywords:

SnSe Thin Films, Thermoelectric Properties, Solar Cells.

Abstract

Tin selenide (SnSe) is a typical layered two-dimensional P-type semiconductor material. Because of its excellent photoelectric and thermoelectric properties and the advantages of its abundant elements in the earth and environ -mentally friendly, it is widely used in solar cells, photoelectric detection, thermoelectric devices and other fields, and has great application prospects in rechargeable batteries. Therefore, the research and application of SnSe thin film has gradually become the current hot spot. This paper first describes the characteristics of SnSe materials, then introduces the research status of SnSe thin films at home and abroad, and studies the preparation methods of three typical SnSe thin films. Finally, it summarizes and prospects the application of SnSe thin films in solar cells, lithium ion batteries, flexible thermoelectric devices and other fields. The appearance of SnSe thin film has once again promoted the remarkable development of photovoltaic industry.

Downloads

Download data is not yet available.

References

[1] Zhao L D, Lo S H, Zhang Y, et al. Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals[J]. nature, 2014, 508(7496): 373-377.

[2] Suen C H, Shi D, Su Y, et al. Enhanced thermoelectric properties of SnSe thin films grown by pulsed laser glancing-angle deposition[J]. Journal of Materiomics, 2017, 3(4): 293-298.

[3] Wang W, Zheng Z, Li F, et al. Synthesis process and thermoelectric properties of n-type tin selenide thin films[J]. Journal of Alloys and Compounds, 2018, 763: 960-965.

[4] Song L, Zhang J, Iversen B B. Enhanced thermoelectric properties of SnSe thin films grown by single-target magnetron sputtering[J]. Journal of Materials Chemistry A, 2019, 7(30): 17981-17986.

[5] Shucong Cui, Shen Honglie, Li Shubing, et al Two step preparation and photoelectric properties of SnSe thin films [J]. Semiconductor Optoelectronics, 2020, 41 (3): 374

[6] Hao L, Du Y, Wang Z, et al. Wafer-size growth of 2D layered SnSe films for UV-Visible-NIR photodetector arrays with high responsitivity[J]. Nanoscale, 2020, 12(13): 7358-7365.

[7] Yan Cui,Qiao Jixiang, Zhao Yang, etc Study on the thermoelectric properties of SnSe thin films prepared by magnetron sputtering deposition [J]Journal of Functional Materials/Gongneng Cailiao, 2021, 52(4).

[8] Urmila K S, Namitha T A, Rajani J, et al. Optoelectronic properties and Seebeck coefficient in SnSe thin films[J]. Journal of Semiconductors, 2016, 37(9): 093002.

[9] Jeong G, Kim J, Gunawan O, et al. Preparation of single-phase SnSe thin-films and modification of electrical properties via stoichiometry control for photovoltaic application[J]. Journal of Alloys and Compounds, 2017, 722: 474-481.

[10] Burton M R, Liu T, McGettrick J, et al. Thin film tin selenide (SnSe) thermoelectric generators exhibiting ultralow thermal conductivity[J]. Advanced Materials, 2018, 30(31): 1801357.

[11] Nguyen T H, Kang R, Pham A T, et al. Se/Sn flux ratio effects on epitaxial SnSe thin films; crystallinity & domain rotation[J]. Journal of Alloys and Compounds, 2020, 840: 155680.

[12] Horide T, Nakamura K, Hirayama Y, et al. Thermoelectric Property of n-Type Bismuth-Doped SnSe Film: Influence of Characteristic Film Defect[J]. ACS Applied Energy Materials, 2021, 4(9): 9563-9571.

[13] Kumar P S S, Sangeetha R, Sivakumar R, et al. Effects of substrate temperature on structural and optoelectronic properties of SnSe thin films by nebulized spray deposition for solar cell applications[J]. Materials Today: Proceedings, 2021, 37: 2763-2769.

[14] Mandal P, Ghorui U K, Mondal A, et al. Photoelectrochemical Performance of Tin Selenide (SnSe) Thin Films Prepared by Two Different Techniques[J]. Electronic Materials Letters, 2022, 18(4): 381-390.

[15] Lihong Yang,Zhang Jian, Fu Jianqin, et al Development status and prospect of new generation continuous strip vacuum coating technology [J]. Steel, 2007, 42(4): 1-4.

[16] Jin Ma,Jia Xiaoming, Shen Jie The influence of zinc magnesium coating preparation and annealing process on zinc magnesium alloy of steel plate [J]. Journal of Vacuum Science and Technology, 2012, 32(4): 332-336.

[17] Deng Zhongyang,Jia Qiang, Feng Bin, et al Progress in Preparation and Application of High Performance Thin Films Prepared by Pulsed Laser Deposition[J]. Chinese Journal of Lasers, 2021, 48(8): 0802010.

[18] Ao Yuhong,Hu Shaoliu, Long Hua, etc. New progress in pulsed laser deposition of thin films [J]. Laser technology, 2003, 27(5): 453-456.

[19] Fourmont P, Gerlein L F, Fortier F X, et al. Highly efficient thermoelectric microgenerators using nearly room temperature pulsed laser deposition[J]. ACS applied materials & interfaces, 2018, 10(12): 10194-10201.

[20] Inoue T, Hiramatsu H, Hosono H, et al. Heteroepitaxial growth of SnSe films by pulsed laser deposition using Se-rich targets[J]. Journal of Applied Physics, 2015, 118(20): 205302.

[21] Franzman M A, Schlenker C W, Thompson M E, et al. Solution-phase synthesis of SnSe nanocrystals for use in solar cells[J]. Journal of the American Chemical Society, 2010, 132(12): 4060-4061.

[22] Abd El-Rahman K F, Darwish A A A, El-Shazly E A A. Electrical and photovoltaic properties of SnSe/Si heterojunction[J]. Materials science in semiconductor processing, 2014, 25: 123-129.

[23] Jamali-Sheini F, Cheraghizade M, Yousefi R. Electrochemically synthesis and optoelectronic properties of Pb-and Zn-doped nanostructured SnSe films[J]. Applied Surface Science, 2018, 443: 345-353.

[24] Jalalian-Larki B, Jamali-Sheini F, Yousefi R. Electrodeposition of In-doped SnSe nanoparticles films: correlation of physical characteristics with solar cell performance[J]. Solid State Sciences, 2020, 108: 106388.

[25] Ling L, Zhang Q, Zhu L, et al. Interfacial synthesis of SnSe quantum dots for sensitized solar cells[J]. RSC Advances, 2015, 5(3): 2155-2158.

[26] Yan Jinding.Development status and prospect analysis of lithium-ion batteries [J]. Journal of Aeronautics, 2014, 35(10): 2767-2775.

[27] Huang Kelong,Wang Zhaoxiang, Liu Suqin. Lithium ion battery principle and key technology [M]. Chemical Industry Press, 2008.

[28] Xue M Z, Yao J, Cheng S C, et al. Lithium electrochemistry of a novel SnSe thin-film anode[J]. Journal of The Electrochemical Society, 2005, 153(2): A270.

[29] [31]Lin Z, Hollar C, Kang J S, et al. A solution processable high‐performance thermoelectric copper selenide thin film[J]. Advanced Materials, 2017, 29(21): 1606662.

[30] Ran Yutong,Chen Wenduo, Zhu Hongwei. Preparation methods, thermoelectric properties and potential applications of SnSe[J]. Chinese Journal of Lasers, 2021, 48(2): 0202015.

[31] Heo S H, Jo S, Kim H S, et al. Composition change-driven texturing and doping in solution-processed SnSe thermoelectric thin films[J]. Nature communications, 2019, 10(1): 864.

[32] Butt F K, Mirza M, Cao C, et al. Synthesis of mid-infrared SnSe nanowires and their optoelectronic properties[J]. CrystEngComm, 2014, 16(17): 3470-3473.

Downloads

Published

2025-02-17

Issue

Section

Articles

How to Cite

Li, Tianhao, and Mengli Li. 2025. “Progress in the Preparation and Application of SnSe Thin Films”. World Scientific Research Journal 11 (3): 152-63. https://doi.org/10.6911/WSRJ.202503_11(3).0016.