Glycerol-Crosslinked Chitosan/Polyvinyl Alcohol/Polyaniline Conductive Hydrogel for Wearable Strain Sensors with High Sensitivity and Environmental Durability

Authors

  • Chengcheng Yang
  • Xue Bai
  • Jifeng Zhang

DOI:

https://doi.org/10.6919/ICJE.202505_11(5).0003

Keywords:

Natural Polysaccharide Hydrogel; Conductive Hydrogel; Flexible Sensor.

Abstract

In this chapter, a PANI/CS/PVA/GL composite conductive hydrogel with excellent mechanical properties, electrical conductivity, and environmental stability was successfully prepared by incorporating conductive polyaniline (PANI) into the chitosan (CS)/polyvinyl alcohol (PVA) hydrogel system, along with the plasticizing and anti-freezing effects of glycerol (GL). Fourier transform infrared spectroscopy (FTIR) analyses confirmed the hydrogen bonding interactions among PANI, CS, and PVA, as well as the successful introduction of PANI. The experimental results demonstrated that the incorporation of PANI not only enhanced the mechanical properties of the hydrogel but also endowed the composite hydrogel with outstanding electrical conductivity. Additionally, the inclusion of glycerol imparted excellent freeze resistance and dehydration resistance to the hydrogel, enabling it to maintain stable mechanical and electrical performance even under extreme environmental conditions.

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References

[1] Cheng, T.; Wang, F.; Zhang, Y.-Z.; Li, L.; Gao, S.-Y.; Yang, X.-L.; Wang, S.; Chen, P.-F.; Lai, W.-Y. 3D Printable Conductive Polymer Hydrogels with Ultra-High Conductivity and Superior Stretchability for Free-Standing Elastic All-Gel Supercapacitors. Chemical Engineering Journal 2022, 450, 138311. https://doi.org/10.1016/j.cej.2022.138311.

[2] Han, X.; Xiao, G.; Wang, Y.; Chen, X.; Duan, G.; Wu, Y.; Gong, X.; Wang, H. Design and Fabrication of Conductive Polymer Hydrogels and Their Applications in Flexible Supercapacitors. J. Mater. Chem. A 2020, 8 (44), 23059–23095. https://doi.org/10.1039/D0TA07468C.

[3] Di Spirito, N. A.; Liu, W.; Di Lorenzo, M.; Grizzuti, N.; Laabei, M.; Leese, H. S.; Pasquino, R. Electrically Conductive and Antimicrobial Pluronic-Based Hydrogels. Journal of Colloid and Interface Science 2025, 679, 544–553. https://doi.org/10.1016/j.jcis.2024.10.005.

[4] Wang, X.; Weng, L.; Zhang, X.; Guan, L.; Li, X. Constructing Conductive and Mechanical Strength Self-Healing Hydrogel for Flexible Sensor. Journal of Science: Advanced Materials and Devices 2023, 8 (3), 100563. https://doi.org/10.1016/j.jsamd.2023.100563.

[5] Khan, B.; Abdullah, S.; Khan, S. Current Progress in Conductive Hydrogels and Their Applications in Wearable Bioelectronics and Therapeutics. Micromachines 2023, 14 (5). https://doi.org/10.3390/mi14051005.

[6] Muxika, A.; Etxabide, A.; Uranga, J.; Guerrero, P.; de la Caba, K. Chitosan as a Bioactive Polymer: Processing, Properties and Applications. International Journal of Biological Macromolecules 2017, 105, 1358–1368. https://doi.org/10.1016/j.ijbiomac.2017.07.087.

[7] Picos-Corrales, L. A.; Morales-Burgos, A. M.; Ruelas-Leyva, J. P.; Crini, G.; García-Armenta, E.; Jimenez-Lam, S. A.; Ayón-Reyna, L. E.; Rocha-Alonzo, F.; Calderón-Zamora, L.; Osuna-Martínez, U.; Calderón-Castro, A.; De-Paz-Arroyo, G.; Inzunza-Camacho, L. N. Chitosan as an Outstanding Polysaccharide Improving Health-Commodities of Humans and Environmental Protection. Polymers 2023, 15 (3). https://doi.org/10.3390/polym15030526.

[8] Wang, X.; Weng, L.; Zhang, X.; Guan, L.; Li, X. Constructing Conductive and Mechanical Strength Self-Healing Hydrogel for Flexible Sensor. Journal of Science: Advanced Materials and Devices 2023, 8 (3), 100563. https://doi.org/10.1016/j.jsamd.2023.100563.

[9] Li, J.; Zhuang, S. Antibacterial Activity of Chitosan and Its Derivatives and Their Interaction Mechanism with Bacteria: Current State and Perspectives. European Polymer Journal 2020, 138, 109984. https://doi.org/10.1016/j.eurpolymj.2020.109984.

[10] Wu, S.; Wang, T.-W.; Du, Y.; Yao, B.; Duan, S.; Yan, Y.; Hua, M.; Alsaid, Y.; Zhu, X.; He, X. Tough, Anti-Freezing and Conductive Ionic Hydrogels. NPG Asia Materials 2022, 14 (1), 65. https://doi.org/10.1038/s41427-022-00410-7.

[11] Lu, P.; Xu, J.; Liu, S.; Fu, L.; Wu, S.; Liu, Z.; Hou, T.; Liu, H.; Huang, D. Facile Synthesis of Ultratough Conductive Gels with Swelling and Freezing Resistance for Flexible Sensor Applications. Scientific Reports 2025, 15 (1), 7335. https://doi.org/10.1038/s41598-025-86541-7.

[12] Shi, J.; Wang, D.; Sarkodie, B.; Wu, D.; Mao, Z.; Liu, Z.; Feng, Q.; Xu, W. Strain Sensors for Human Movement Detection Based on Fibrous Membranes Comprising Thermoplastic Polyurethane, Ag Nanoparticles, and Carbon Nanotubes. ACS Appl. Nano Mater. 2024, 7 (2), 2051–2061. https://doi.org/10.1021/acsanm.3c05335.

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Published

2025-04-22

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Section

Articles

How to Cite

Yang, Chengcheng, Xue Bai, and Jifeng Zhang. 2025. “Glycerol-Crosslinked Chitosan Polyvinyl Alcohol Polyaniline Conductive Hydrogel for Wearable Strain Sensors With High Sensitivity and Environmental Durability”. International Core Journal of Engineering 11 (5): 18-26. https://doi.org/10.6919/ICJE.202505_11(5).0003.