Research Progress of Heteroatoms-Doped Carbon-Based Materials for Capacitive Deionization
DOI:
https://doi.org/10.6919/ICJE.202505_11(5).0025Keywords:
Capacitive Deionization; Heteroatoms-Doped; Carbon-Based Materials.Abstract
The shortage of fresh water resources has become one of the most concerned issues in the world. Various water treatment technologies have been developed to desalinate seawater, and capacitive deionization (CDI) has attracted wide attention as a new electro-adsorption desalination technology. However, electrode materials are an important factor affecting the performance of CDI. In recent years, considerable research progress has been made in the rational design and manufacture of heteroatom-doped carbon materials used as CDI electrode materials. In this paper, the latest research progress of heteroatom-doped graphene, carbon nanofibers and activated carbon is systematically reviewed. In addition, the challenges and possible future development in the field of CDI are briefly prospected for researchers to design carbon-based electrode materials for practical application.
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[1] AGARTAN L, AKUZUM B, MATHIS T, et al. Capacitive Deionization Performance of Thermally Surface Modified Activated Carbon Cloth Electrodes [J]. ECS Meeting Abstracts, 2017, MA2017-02(54):2259.
[2] GAIKWAD M S, BALOMAJUMDER C, TIWARI A K. Acid treated RHWBAC electrode performance for Cr(VI) removal by capacitive deionization and CFD analysis study [J]. Chemosphere, 2020, 254:126781.
[3] YASIN A S, MOHAMED A Y, MOHAMED I M A, et al. Theoretical insight into the structure-property relationship of mixed transition metal oxides nanofibers doped in activated carbon and 3D graph ene for capacitive deionization [J]. Chemical Engineering Journal, 2019.
[4] OLADUNNI J, ZAIN J H, HAI A, et al. A comprehensive review on recently developed carbon based nanocomposites for capacitive deionization: From theory to practice [J]. Separation and Purification Technology, 2018, 207:291-320.
[5] AL RADI M, SAYED E T, ALAWADHI H, et al. Progress in energy recovery and graphene usage in capacitive deionization [J]. Critical Reviews in Environmental Science and Technology, 2021, 52(17):3080-3136.
[6] TANG K, YIACOUMI S, LI Y, et al. Enhanced Water Desalination by Increasing the Electroconductivity of Carbon Powders for High-Performance Flow-Electrode Capacitive Deionization [J]. ACS Sustainable Chemistry & Engineering, 2019, 7(1):1085-1094.
[7] ZHANG H, WANG C, ZHANG W, et al. Nitrogen, phosphorus co-doped eave-like hierarchical porous carbon for efficient capacitive deionization [J]. Journal of Materials Chemistry A, 2021, 9(21):12807-12817.
[8] LIANG J, JIAO Y, JARONIEC M, et al. Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance [J] . Angewandte Chemie International Edition, 2012, 51(46):11496-11500.
[9] QIAN M, DUAN M, GONG Z. Nitrogen-doped self-shrinking porous 3D graphene capacitor deionization electrode [J]. International Journal of Energy Research, 2019, 43(13):7583-7593.
[10] XU X, SUN Z, CHUA D H C, et al. Novel nitrogen doped graphene sponge with ultrahigh capacitive deionization performance [J]. Scientific Reports, 2015, 5(1):11225.
[11] ZHANG G, LI W, CHEN Z, et al. Freestanding N-doped graphene membrane electrode with interconnected porous architecture for efficient capacitive deionization [J]. Carbon, 2022, 187:86-96.
[12] LIU S, LI B, ZHOU Y, et al. Hierarchical N-doped holey three-dimensional reduced graphene oxide with high performance capacitive deionization [J]. Journal of Materials Research and Technology, 2021, 15:1996-2006.
[13] JING L, LU Y, JIANG J, et al. Constructing a high-performance nitrogen-doped three-dimensional framework graphene material for efficient capacitive deionization [J]. Desalination, 2024, 576:117382.
[14] JIANG T, ZHAI H, YANG K, et al. Nitrogen-doped porous graphene electrodes for highly efficient capacitive deionization [J]. International Journal of Electrochemical Science, 2024, 19(1):100434.
[15] HAN D-C, ZHANG C-M, GUAN J, et al. High-performance capacitive deionization using nitrogen and phosphorus-doped three-dimensional graphene with tunable pore size [J]. Electrochimica Acta, 2020, 336:135639.
[16] MAMARIL G S S, DE LUNA M D G, BINDUMADHAVAN K, et al. Nitrogen and fluorine co-doped 3-dimensional reduced graphene oxide architectures as high-performance electrode material for capacitive deioniz ation of copper ions [J]. Separation and Purification Technology, 2021, 272:117559.
[17] LUO Q, WANG K, YANG Y, et al. Constructing interconnected hierarchical porous structures and nitrogen-doped carbon nanofibers for superior capacitive deionization [J] . Journal of Colloid and Interface Science, 2025, 681:95-105.
[18] CHEN D, YANG L, ZHANG Z, et al. Iron nanoparticle embedded carbon nanofibers as flexible electrodes for selective chloride ions capture in capacitive deionization [J]. Desalination, 2024, 573:117175.
[19] GAO L, LIU S, DONG Q, et al. Sulfur & nitrogen co-doped electrospun carbon nanofibers as freestanding electrodes for membrane capacitive deionization [J]. Separation and Purification Technology, 2022, 295:121280.
[20] LIU X, ZHAO B, HU Y, et al. Enhancing capacitive deionization performance and cyclic stability of nitrogen-doped activated carbon by the electro-oxidation of anode materia ls [J]. Chinese Journal of Chemical Engineering, 2024, 69:23-33.
[21] ZHAO F, CHEN S, XIANG H, et al. Selectively capacitive recovery of rare earth elements from aqueous solution onto Lewis base sites of pyrrolic-N doped activated carbon electrodes [J]. Carbon, 2022, 197:282-291.
[22] HSU C-C, TU Y-H, YANG Y-H, et al. Improved performance and long-term stability of activated carbon doped with nitrogen for capacitive deionization [J]. Desalination, 2020, 481:114362.
[23] WANG S, CHEN D, ZHANG Z-X, et al. Mesopore dominated capacitive deionization of N-doped hierarchically porous carbon for water purification [J]. Separation and Purification Technology, 2022, 290:120912.
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